A new solar material that has the same crystal structure as a mineral first found in the Ural Mountains in 1839 is shooting up the efficiency charts faster than almost anything researchers have seen before—and it is generating optimism that a less expensive way of using sunlight to generate electricity may be in our planet’s future.
Researchers at the Energy Department’s National Renewable Energy Laboratory (NREL) are analyzing the new material, perovskite, using the lab’s unique testing capabilities and broad spectrum of expertise to uncover the secrets and potential of the semiconducting cube-like mineral.
NREL has already produced three scientific papers on perovskite, reporting on the science behind the very large length of the electron pairs (or charge diffusion length) in mesostructured perovskite solar cells. The two most-studied perovskite device structures are mesostructured (of medium complexity) and planar (two-dimensional). NREL Research Fellow David Ginley, who is a world-renowned materials scientist and winner of several R&D 100 Awards, said what makes perovskite device structures so remarkable is that when processed in a liquid solution, they have unusual abilities to diffuse photons a long distance through the cell. That makes it far less likely that the electrons will recombine with their hole pairs and be lost to useful electricity. And that indicates a potential for low-cost, high-efficiency devices.
NREL Senior Scientist Daniel Friedman notes that the light-absorbing perovskite cells have “a diffusion length 10 times longer than their absorption length,” not only an unusual phenomenon, but a very useful one, too.